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Method Summary

Method Source U.S. EPA National Exposure Research Laboratory (NERL) [formerly EMSL]
Method Number150.1
Revision InformationIssued 1971; Editorial Revision 1978 and 1982
Method NameDescriptive Name: pH in Water by Electrometric Method

Official Name: pH, Electrometric Method

MediaMedia: WATER
SubcategoryInorganic
Citation Methods for the Chemical Analysis of Water and Wastes (MCAWW) (EPA/600/4-79/020)
Method Download Adobe Acrobat (pdf) icon Download full method now (PDF file)
Summary of MethodThe pH of a sample is determined electrometrically using either a glass electrode in combination with a reference potential or a combination electrode.
Scope and ApplicationThis method determines the pH of drinking, surface and saline water; and domestic and industrial wastes and acid rain (atmospheric deposition).
Applicable Concentration RangeNone given.
Interferences(1) Sodium error may bias results at pH > 10 unless a "low sodium error" electrode is used. (2) Coatings of oily material can impair electrode. (3) Temperature effects.
QC Requirementsnot included
Sample HandlingCollect a volume of 25 mL in glass or plastic bottles. No preservation is required. The samples should be analyzed as soon as possible after collection, preferably in the field.
Max Holding TimeASAP
Relative Cost/EffortLess than $50
Sample Prep Method(s) 
 

Method pH in Water by Electrometric Method has 1 analytes associated with it.

Analyte


Detection
Level


Bias Precision Pct False
Positive
pH
(E-10139)
N/A100 % Rec (ML).8 % RSD (ML)5 pH
export_analytes
Precision Descriptor NotesPrecision and accuracy values were calculated using interlaboratory data from EPA-managed Water Pollution (WP) performance evaluation studies.
Detection Level Note -
 
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